If you are using a PWM RC receiver so that each channel has it's own signal wire (vs. anything else where all signals are on the same wire and must be decoded), then the easy thing to do is connect this straight to your RC receiver spare channel, test it by moving the channel to prove that you can turn it on and off, and finally, program your RC failsafe to set that channel to the value that makes it work.
Be aware that most modern RC systems must be programmed to get the switches to do anything. The default is that the switches don't do anything at all. Read your RC instructions.
If you are using any other kind of receiver (SBus, PPM, etc.) , you must use the CC3D to decode the signal and put it out as a PWM signal, typically on an unused ESC connection (there are 6 sets of connections and you are only using 4 to actually connect to ESCs).
Set Configuration -> Vehicle ->Accessory0 to the number of the unused ESC connector (probably 5 or 6). Make sure the Input page and Output page have reasonable values for it. For PPM Input the values are the same as for PWM Input, 1000 1500 2000 but this might be different for other input protocols. It should be obvious from the other channels what the new channel should be. Output probably must have 1000 1500 2000. See the first paragraph about testing the channel and setting the RC failsafe.